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This important book describes the basic principles of astrochemistry—an interdisciplinary field combining astronomy, physics, and chemistry—with particular emphasis on its physical and chemical background. Chemical processes in diffuse clouds, dense quiescent molecular clouds, star-forming regions, and protoplanetary disks are discussed. A brief introduction to molecular spectroscopy and observational techniques is also presented. These contents provide astronomers with a comprehensive understanding of how interstellar matter is evolved and brought into stars and planets, which is ultimately related to the origin of the solar system. The subject matter will also be understandable and useful for physical chemists who are interested in exotic chemical processes occurring in extreme physical conditions. The book is a valuable resource for all researchers beginning at the graduate level.
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Gas-phase ion chemistry is a broad field which has many applications and which encompasses various branches of chemistry and physics. An application that draws together many of these branches is the synthesis of molecules in interstellar clouds. This was part of the motivation for studies on the neutralization of ions by electrons and on isomerization in ion-neutral associations. The results of investigations of particular aspects of ion dynamics are presented in this volume. Solvation in ion-molecule reactions is discussed and extended to include multiply charged ions by the application of electrospray techniques. This volume also provides a wealth of information on reaction thermodynamics which is critical in determining reaction spontaneity and availability of reaction channels. More focused studies are also presented towards the end of this volume, relating to the ionization process and its nature.
The annual meeting of the Astronomische Gesellschaft in Cologne, June 1988, featured extensive reviews of the chemical processes relevant to astrophysics. The twelve contributions to this book, written by experts from the US, UK, France, Belgium, Switzerland and Germany, deal in depth with the chemistry of comets and meteorites, of stars and their shells, of the interstellar medium and galaxies. A comprehensive review of nucleosynthesis and two reports on observations round off an up-to-date presentation of cosmic chemistry.
The physical and chemical processes leading to the formation of molecules in the interstellar medium, as well as in solar system planetary and satellite atmospheres, has fascinated scientists for many years. This conference set out to shed light on the basic question "How are these molecules actually formed in these extraterrestrial environments?" Topics included are: Gas phase laboratory experiments; solid state laboratory experiments; observations and spectroscopy, as well as modeling and theory.